Organometallic Chemistry and CatalysisSpringer Science & Business Media, 2007 M08 2 - 608 pages This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title. |
Contents
Introduction | 2 |
and the golden age of catalysis | 10 |
Current trends | 18 |
Bimetallic transitionmetal complexes and clusters | 47 |
Clusters | 60 |
The isolobal analogy | 73 |
PART II | 78 |
Reactions of nucleophiles and electrophiles with complexes 109 1 Nucleophilic reactions | 109 |
Group 14 Si Ge Sn Pb | 328 |
Group 15 As Sb Bi | 340 |
Summary and Exercises | 346 |
Hydrogenation and hydroelementation of alkenes | 357 |
Hydroamination of olefins and alkynes | 363 |
Metathesis of alkenes alkynes and cycloalkenes | 373 |
Olefin dimerization and oligomerization | 386 |
Summary and Exercises | 392 |
Reactions of electrophiles | 115 |
Electrontransferchain and atomtransferchain mechanisms | 127 |
Summary and Exercises | 133 |
Methylene insertion and extrusion | 139 |
Summary and Exercises | 146 |
Metalalkyl and hydride complexes | 148 |
and other complexes of monohapto X ligands | 175 |
Synthesis of metalalkyl complexes | 179 |
Properties of metalalkyl complexes | 180 |
Metallocycles | 181 |
Metalaryl vinyl alkynyl silyl and stannyl complexes | 182 |
Metalhydrides and the dihydrogen ligand | 184 |
Alkoxy and amido complexes | 193 |
Summary and Exercises | 194 |
Metalcarbene and carbyne complexes and multiple bonds with transition metals 197 | 196 |
APPLICATIONS IN ORGANIC SYNTHESIS | 214 |
Metalcarbyne complexes | 215 |
oxo imido phosphinidene and nitrido ligands | 217 |
Summary and Exercises | 223 |
complexes of mono and polyenes and enyls | 225 |
Metaldiene complexes and analogues | 228 |
Metalalkyne complexes | 231 |
Allyl complexes | 233 |
Polyenyl complexes | 237 |
Arene complexes | 243 |
Summary and Exercises | 248 |
Metallocenes and sandwich complexes | 251 |
Redox properties of the sandwich metallocenes | 255 |
Metallocene synthesis | 256 |
Chemical properties of metallocenes | 258 |
Triple and multipledecker sandwich complexes | 266 |
Nonsandwich metallocenes derivatives | 268 |
Metalbisarene sandwich complexes | 270 |
Cylopentadienylmetalarene complexes | 274 |
Summary and Exercises | 287 |
alkali and rareearth complexes | 289 |
of frontier 11 12 and main 1316 groups 313 | 312 |
Group 13 B Al Ga In Tl | 320 |
Oxidation of olefins | 395 |
Wacker process | 396 |
Epoxidation of olefins | 399 |
Hydroxylation by metaloxo complexes | 402 |
Phasetransfer catalysis in oxidation chemistry | 405 |
Summary and Exercises | 407 |
CH activation and functionalization of alkanes and arenes | 409 |
Alkanes and cycloalkanes | 410 |
Aromatics | 419 |
Summary and Exercises | 428 |
Carbonylation and carboxylation reactions 431 | 430 |
oxo process | 433 |
the Reppe reaction | 434 |
Carbonylation of aryl halides in the presence of a nucleophile | 436 |
Catalysis of CO2 transformation | 437 |
Summary and Exercises | 438 |
enzymatic catalysis | 441 |
coenzyme vitamin B12 | 442 |
Biological redox mediators | 445 |
the monooxygenases | 446 |
Nitrogen fixation by nitrogenase enzyme | 449 |
Nickel enzymes | 452 |
Summary and Exercises | 455 |
Heterogeneous catalysis | 457 |
Concepts of heterogeneous catalysis | 460 |
CO and CO2 hydrogenation and FischerTropsch chemistry | 469 |
Transformation of hydrocarbons | 475 |
Metathesis of alkanes alkenes and alkynes | 477 |
Oxidation of hydrocarbons | 480 |
the fast growing frontier between homogeneous and heterogeneous catalysis | 483 |
Summary and Exercises | 485 |
Organometallic complexes in organic synthesis | 488 |
for the formation of cyclic and heterocyclic compounds | 518 |
Summary and Exercises | 530 |
553 | |
Abbreviations 591 | 590 |
Atomic weights of the elements | 609 |
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Common terms and phrases
18-electron complexes 18-electron rule agostic alcohols alkane alkene alkyl alkylidene alkyne metathesis allyl amines anion arene aromatic aryl backbonding benzene bond metathesis bridging C-H activation C-H bond carbene catalyst cation Chap Chem clusters compounds coordination coupling deprotonation derivatives dimerization double bond electrophilic enzymes epoxidation ethylene example Fe Fe Fe Fe OC FeII FeIII ferrocene formation fragments give H atom halides heterogeneous hydride hydrocarbons hydrogenation inorganic insertion instance intermediate involving kcal lanthanides ligand mechanism metal carbonyls metal center metal-alkyl complexes metal-carbene complexes metallocenes methyl molecular molecule nucleophilic OC OC olefin olefin metathesis orbital organic synthesis Organomet organometallic chemistry oxidative addition oxygen Ph Ph phosphines polymerization PPh3 propene protonation radical react reaction reactive reagent redox reductive elimination ring Schrock solvent species stable steric structure substitution substrates surface t-Bu transition metals transition-metal valence electrons