Organometallic Chemistry and CatalysisSpringer Science & Business Media, 2007 M08 14 - 608 pages This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title. |
Contents
2 | |
10 | |
18 | |
Bimetallic transitionmetal complexes and clusters | 47 |
Clusters | 60 |
The isolobal analogy | 73 |
PART II | 78 |
Reactions of nucleophiles and electrophiles with complexes 109 1 Nucleophilic reactions | 109 |
Group 14 Si Ge Sn Pb | 328 |
Group 15 As Sb Bi | 340 |
Summary and Exercises | 346 |
Hydrogenation and hydroelementation of alkenes | 357 |
Hydroamination of olefins and alkynes | 363 |
Metathesis of alkenes alkynes and cycloalkenes | 373 |
Olefin dimerization and oligomerization | 386 |
Summary and Exercises | 392 |
Reactions of electrophiles | 115 |
Electrontransferchain and atomtransferchain mechanisms | 127 |
Summary and Exercises | 133 |
Methylene insertion and extrusion | 139 |
Summary and Exercises | 146 |
Metalalkyl and hydride complexes | 148 |
and other complexes of monohapto X ligands | 175 |
Synthesis of metalalkyl complexes | 179 |
Properties of metalalkyl complexes | 180 |
Metallocycles | 181 |
Metalaryl vinyl alkynyl silyl and stannyl complexes | 182 |
Metalhydrides and the dihydrogen ligand | 184 |
Alkoxy and amido complexes | 193 |
Summary and Exercises | 194 |
Metalcarbene and carbyne complexes and multiple bonds with transition metals 197 | 196 |
APPLICATIONS IN ORGANIC SYNTHESIS | 214 |
Metalcarbyne complexes | 215 |
oxo imido phosphinidene and nitrido ligands | 217 |
Summary and Exercises | 223 |
complexes of mono and polyenes and enyls | 225 |
Metaldiene complexes and analogues | 228 |
Metalalkyne complexes | 231 |
Allyl complexes | 233 |
Polyenyl complexes | 237 |
Arene complexes | 243 |
Summary and Exercises | 248 |
Metallocenes and sandwich complexes | 251 |
Redox properties of the sandwich metallocenes | 255 |
Metallocene synthesis | 256 |
Chemical properties of metallocenes | 258 |
Triple and multipledecker sandwich complexes | 266 |
Nonsandwich metallocenes derivatives | 268 |
Metalbisarene sandwich complexes | 270 |
Cylopentadienylmetalarene complexes | 274 |
Summary and Exercises | 287 |
alkali and rareearth complexes | 289 |
of frontier 11 12 and main 1316 groups 313 | 312 |
Group 13 B Al Ga In Tl | 320 |
Oxidation of olefins | 395 |
Wacker process | 396 |
Epoxidation of olefins | 399 |
Hydroxylation by metaloxo complexes | 402 |
Phasetransfer catalysis in oxidation chemistry | 405 |
Summary and Exercises | 407 |
CH activation and functionalization of alkanes and arenes | 409 |
Alkanes and cycloalkanes | 410 |
Aromatics | 419 |
Summary and Exercises | 428 |
Carbonylation and carboxylation reactions 431 | 430 |
oxo process | 433 |
the Reppe reaction | 434 |
Carbonylation of aryl halides in the presence of a nucleophile | 436 |
Catalysis of CO2 transformation | 437 |
Summary and Exercises | 438 |
enzymatic catalysis | 441 |
coenzyme vitamin B12 | 442 |
Biological redox mediators | 445 |
the monooxygenases | 446 |
Nitrogen fixation by nitrogenase enzyme | 449 |
Nickel enzymes | 452 |
Summary and Exercises | 455 |
Heterogeneous catalysis | 457 |
Concepts of heterogeneous catalysis | 460 |
CO and CO2 hydrogenation and FischerTropsch chemistry | 469 |
Transformation of hydrocarbons | 475 |
Metathesis of alkanes alkenes and alkynes | 477 |
Oxidation of hydrocarbons | 480 |
the fast growing frontier between homogeneous and heterogeneous catalysis | 483 |
Summary and Exercises | 485 |
Organometallic complexes in organic synthesis | 488 |
for the formation of cyclic and heterocyclic compounds | 518 |
Summary and Exercises | 530 |
553 | |
Abbreviations 591 | 590 |
Atomic weights of the elements | 609 |
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Common terms and phrases
18-electron acid active alcohols alkane alkene alkyl alkyne allows allyl analogous anion applications arene aromatic atom attack bond bridging carbene carbonyl catalyst cation Chap Chapter Chem chemistry Cl Cl clusters complexes compounds containing coordination coupling deprotonation derivatives dimerization double electrons electrophilic energy ethylene example Fe Fe Fe ferrocene formation fragments functional give halides heterogeneous hydride hydrogenation important initiation insertion instance intermediate involving known latter leads less ligand mechanism metal-alkyl metathesis molecular nucleophilic obtained occurs olefin orbital organic organometallic oxidative addition oxygen polymerization possible PPh3 presence properties radical reaction reactive reagent redox reduction reductive elimination resulting ring sandwich selectivity shown shows solvent species stable step strong structure substitution substrates surface synthesis terminal transfer transition metals transition-metal usually valence various whereas yield
Popular passages
Page 554 - F. Basolo and RG Pearson, Mechanisms of Inorganic Reactions, 2nd ed., Wiley New York, 1967.